Aqueous corrosion of phosphide minerals from iron meteorites: a highly reactive source of prebiotic phosphorus on the surface of the early Earth

We present the results of an experimental study of aqueous corrosion of Fe-phosphide under conditions relevant to the early Earth. The results strongly suggest that iron meteorites were an important source of reactive phosphorus (P), a requirement for the formation of P-based life. We further demonstrate that iron meteorites were an abundant source of phosphide minerals early in Earth history. Phosphide corrosion was studied in five different solutions: deionized water, deionized water buffered with sodium bicarbonate, deionized water with dissolved magnesium and calcium chlorides, deionized water containing ethanol and acetic acid, and deionized water containing the chlorides, ethanol, and acetic acid. Experiments were performed in the presence of both air and pure Ar gas to evaluate the effect of atmospheric chemistry. Phosphide corrosion in deionized water results in a metastable mixture of mixed-valence, P-bearing ions including pyrophosphate and triphosphate, key components for metabolism in modern life. In a pH-buffered solution of NaHCO(3), the condensed and reduced species diphosphonate is an abundant corrosion product. Corrosion in ethanol- and acetic acid-containing solutions yields additional P-bearing organic molecules, including acetyl phosphonate and a cyclic triphosphorus molecule. Phosphonate is a major corrosion product of all experiments and is the only P-bearing molecule that persists in solutions with high concentrations of magnesium and calcium chlorides, which suggests that phosphonate may have been a primitive oceanic source of P. The stability and reactivity of phosphonate and hypophosphite in solution were investigated to elucidate reaction mechanisms and the role of mineral catalysts on P-solution chemistry. Phosphonate oxidation is rapid in the presence of Fe metal but negligible in the presence of magnetite and in the control sample. The rate of hypophosphite oxidation is independent of reaction substrate.     

Microgravity effects on water supply and substrate properties in porous matrix root support systems.

The control of water content and water movement in granular substrate-based plant root systems in microgravity is a complex problem. Improper water and oxygen delivery to plant roots has delayed studies of the effects of microgravity on plant development and the use of plants in physical and mental life support systems. Our international effort (USA, Russia and Bulgaria) has upgraded the plant growth facilities on the Mir Orbital Station (OS) and used them to study the full life cycle of plants. The Bulgarian-Russian-developed Svet Space Greenhouse (SG) system was upgraded on the Mir OS in 1996. The US developed Gas Exchange Measurement System (GEMS) greatly extends the range of environmental parameters monitored. The Svet-GEMS complex was used to grow a fully developed wheat crop during 1996. The growth rate and development of these plants compared well with earth grown plants indicating that the root zone water and oxygen stresses that have limited plant development in previous long-duration experiments have been overcome. However, management of the root environment during this experiment involved several significant changes in control settings as the relationship between the water delivery system, water status sensors, and the substrate changed during the growth cycles.     

Metabolic assessments during extra-vehicular activity

Extra-vehicular activity (EVA) has a significant role during extended space flights. It demonstrates that humans can survive and perform useful work outside the Orbital Space Stations (OSS) while wearing protective space suits (SS). When the International Space Station 'Alpha' (ISSA) is fully operational, EVA assembly, installation, maintenance and repair operations will become an everyday repetitive work activity in space. It needs new ergonomic evaluation of the work/rest schedule for an increasing of the labor amount per EVA hour. The metabolism assessment is a helpful method to control the productivity of the EVA astronaut and to optimize the work/rest regime. Three following methods were used in Russia to estimate real-time metabolic rates during EVA: 1. Oxygen consumption, computed from the pressure drop in a high pressure bottle per unit time (with actual thermodynamic oxygen properties under high pressure and oxygen leakage taken into account). 2. Carbon dioxide production, computed from CO2 concentration at the contaminant control cartridge and gas flow rate in the life support subsystem closed loop (nominal mode) or gas leakage in the SS open loop (emergency mode). 3. Heat removal, computed from the difference between the temperatures of coolant water or gas and its flow rate in a unit of time (with assumed humidity and wet oxygen state taken into account). Comparison of heat removal values with metabolic rates enables us to determine the thermal balance during an operative medical control of EVA at "Salyut-6", "Salyut-7" and "Mir" OSS. Complex analysis of metabolism, body temperature and heat rate supports a differential diagnosis between emotional and thermal components of stress during EVA. It gives a prognosis of human homeostasis during EVA. Available information has been acquired into an EVA data base which is an effective tool for ergonomical optimization.     

Media reaction to a SETI success

Consideration of the reaction to a SETI detection by the media, and the effect this will have on the public, is more than mere sociological speculation. An accurate forecast of the media's interest can lead to actions that will help ensure that correct and comprehensible information reaches the public. This is most critical in the first few weeks following a discovery. While a widely accepted protocol for dealing with a detection exists in the "Declaration of Principles Following the Detection of Extraterrestrial Intelligence," it gives scant consideration to the fact that the actual situation will be chaotic and not subject to easy control. The 1996 story about the possible discovery of martian microfossils has provided a useful precedent for what will happen if astronomers uncover the existence of alien intelligence.     

The Soviet manned lunar programme and its legacy

In the last two years the USSR has not only acknowledged publicly for the first time that it was trying to ‘race’ the USA to put the first man on the Moon, but they have finally given some details of the programme, the equipment and the political in-fighting which ensured that the programme was a failure. This article traces the history of the Soviet manned lunar programme and also discusses the implications for the future development of the Soviet manned programme of the giant N-1 booster's cancellation in 1974.     

Low-velocity detonations in cast and pressed high explosives

A model of low velocity detonations in charges of cast and pressed high explosives confined in metal tubes with thin walls is suggested. An analytical solution is obtained and velocities and pressures of stationary LVD waves are calculated as functions of the parameters of the wall confinement. The fraction of the total chemical energy transferred to maintain the shock wave and the average rate of reaction in the wave are estimated and the dynamics of transient predetonation processes are analysed. An explanation of the causes of the secondary shock wave formation in the transition from deflagration to normal detonations is suggested and the delay of this secondary wave is calculated and compared with experimental data.     

Transport Characteristics of Macroparticles in Dusty Plasma Induced by Solar Radiation under Microgravity Conditions

The transport characteristics of macroparticles, charged by the solar radiation under microgravity conditions, were investigated by analyzing the videorecords of experiments carried out onboard the Mirorbital station. The temperature, distributions of velocities, charge, friction coefficient, and diffusion coefficient were obtained for bronze particles.     

Radio Occultation Measurements of the Radio Wave Absorption and the Sulfuric Acid Vapor Content in the Atmosphere of Venus

The results of the determination of centimeter ( = 5 cm) radio waves absorption in the radio occultation experiments, carried out using the Venera-15and Venera-16spacecraft, are presented. The altitude distribution of the absorber substance is analyzed. The absorbing layer is shown to exist at altitudes of 64 to 58 km in the near-polar regions of the planet. At middle latitudes such an absorbing layer was not found. In the altitude range from 56 to 46 km the radio wave absorption by the sulfuric acid (H₂SO₄) vapor is observed. The content of the sulfuric acid vapor is shown to increase with decreasing altitude: in the mid-latitude region at altitudes of 56.7 and 53 km it equals 5 and 20 ppm, respectively, and at polar latitudes the same content of H₂SO₄vapor is observed at altitudes of 51.2 and 47 km, respectively. A comparison of these results with the data of radio wave absorption in the = 13 cm band, obtained in the Pioneer Venus Orbiterradio occultation experiments, leads to the conclusion that the obtained values of the sulfuric acid vapor content well agree in the regions of overlap of the data.     

Influence of Trapped Plasma on the Structure of Collisionless Thin Current Sheets

Using both analytical and numerical models of the collisionless anisotropic current sheet generated by the impinging flows of transient ions, we have studied the self-consistent solutions taking the plasma trapped in the sheet into account. It is demonstrated that there exists a limited window in the space of system parameters where self-consistent solutions can exist. When the density of the quasi-trapped plasma is sufficiently large, a redistribution of the total current can be a cause of the sheet decay, when the local current of the trapped particles compensate (totally or in part) the main current in the center and at the edges of the sheet, while the total current generated by ions on the trapped trajectories vanishes.     

Surreal estate: addressing the issue of ‘Immovable Property Rights on the Moon’

At a time when scientific and commercial interest in the Moon is being reinvigorated it is becoming fashionable for ordinary individuals to ‘buy’ plots on the lunar surface, with the ‘vendors’ arguing that an absence of specific prohibition of individual private activity in space makes such action legal. It is therefore time for the legal community to address this situation by investigating just how legal such activity is—and bringing their findings to the attention of governments. This can be done through an examination of the relationship between national law and international space law, of the provisions of international space law—especially Article 2 of the Outer Space Treaty—and by answering any claims to private ownership of immovable property. Aside from the fact that individuals appear to be being duped, the pursuit of property claims on the Moon could impede future activities aimed at benefiting society.